Respuesta :
Answer is: carbon tetrachloride has the greatest boiling point elevation.
The boiling point elevation is directly proportional to the molality of the solution according to the equation: ΔTb = Kb · b.
ΔTb - the boiling point elevation.
Kb - the ebullioscopic constant.
b - molality of the solution.
So the highest boiling poing elevation will be for solution with highest ebullioscopic constant because molality is the same.
The boiling point elevation is directly proportional to the molality of the solution according to the equation: ΔTb = Kb · b.
ΔTb - the boiling point elevation.
Kb - the ebullioscopic constant.
b - molality of the solution.
So the highest boiling poing elevation will be for solution with highest ebullioscopic constant because molality is the same.
Carbon tetrachloride, CCl₄ Kb = 5.03 ° c / m, would show the greatest boiling point elevation when used to make a 0.10 m nonelectrolyte solution
Further explanation
Colligative properties are the properties of a solution that do not depend on the type of solute but only on the concentration of the solute.
Colligative properties of electrolyte solutions differ from non-electrolyte solutions because electrolyte solutions contain a greater number of particles because electrolytes break down into ions. So the colligative properties of electrolytes is greater than non-electrolytes.
The term used in the colligative properties
- 1. molal
that is, the number of moles of solute in 1 kg of solvent
[tex]\large{\boxed{\bold{m=mole. \frac{1000}{ mass\:of\:solvent (in\:grams)}}}[/tex]
- 2. mole fraction
the ratio of the number of moles of solute to the mole of solution
[tex]\large{\boxed{\bold{Xa=\frac{na}{na+nb} }}[/tex]
- 3. Vapour pressure
Vapor pressure depends on the mole fraction of the components in the solution
Pa = Xa. P °
Pa = vapor pressure component A
P ° = pure vapor pressure
Xa = mole fraction A
ΔP = P ° - P where
ΔP = change in vapor pressure
- 4. Boiling point and freezing point
Solutions from volatile substances have a higher boiling point and lower freezing point than the solvent
ΔTb = Tb solution - Tb solvent
ΔTb = boiling point elevation
[tex]\large{\boxed{\boxed{\bold{\Delta Tb\:=\:Kb.m}}}[/tex]
ΔTf = Kf.m
Kb = molal boiling point constant
Kf = molal freezing point constant
m = molal solution
From the Boiling Point Elevation Equation shows that the value of the change in the boiling point of the solution depends on:
• 1. The concentration of the solution is molal
• 2. molal boiling point constant value
Of the compounds in question, carbon tetrachloride (CCl₄), has the largest Kb of 5.03 ° c / m, so that the boiling point changes are greatest because the amount of molal concentration of the solution to be made is equal to = 0.1 m
Learn more
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Keywords: Freezing Point Depression, Boiling Point Elevation, Colligative Properties