Respuesta :

It is due to their more extensive association of carboxylic acid via van der Waals force of attraction.

Carboxylic acids have better boiling point than carbonyl compounds and alcohols because of the presence of intramolecular hydrogen bonding.

The boiling factors are decrease than alcohols or carboxylic acids because aldehydes and ketones are polar compounds having sufficient intermolecular dipole-dipole interactions among opposite ends of C=O. dipoles.

The quite paradoxical final results of that is that carboxylic acids are more potent acids than alcohols because carboxylate ions, their conjugate bases, are weaker bases than alkoxides. that is due in massive part to resonance stabilization of the carboxylate ions, which can't take place in alkoxides.

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