Annette experienced something unexpected, which caused her to express her emotion as "surprised."
Annette experienced something unexpectedly, which left her feeling both surprised and amazed.
Annette was shocked by an unexpected experience that left her speechless. She was astonished, but her response was more severe.
The three words all roughly mean the same thing when describing someone who runs into an unexpected situation.
The word "astonish" frequently denotes a stronger reaction to a circumstance that can progress to shock. Unlike astounded, surprised occasionally has a bad connotation. One would be more shocked to encounter a ghost (being shocked that they saw a ghost unexpectedly).
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