The number of π molecular orbitals in a molecule is always equal to the number of p orbitals used to construct the π bonds.
An electron's position and wave-like behavior within a molecule are described by a mathematical function called a molecular orbital. Chemical, as well as physical properties like the probability of locating an electron in a particular area, can be determined using this function.
A molecular orbital would be created when two atomic orbitals cross one other along the internuclear axis. A molecular orbital is created when two atomic orbitals cross each other sideways.
Therefore, the number of π molecular orbitals in a molecule is always equal to the number of p orbitals used to construct the π bonds.
Hence, the correct answer will be option (a).
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