When particles move fast enough, these forces can no longer keep particles together.
Recall that the particles of a substance are in constant random motion. Hence, when more energy is added to the system, the particles within the system will have greater motion, and the temperature will increase.
The forces that keep molecules together in a particular state of matter are electrostatic forces. When particles move fast enough, these forces can no longer keep particles together.
It is common to use the analogy of an elastic material to represent the bonding between atoms in molecules. However, this analogy is not apt in a phase change because, for a phase change from liquid to gas, the bonds break completely and particles can move independently of each other.
We know that the average kinetic energy of the molecules of a substance depends on the temperature of the body. Therefore, a sample of liquid benzene at 80ºC and a sample of gaseous benzene at 80ºC will have the same average kinetic energy as benzene molecules.
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