Answer:
The correct answer is 1.21 L.
Explanation:
Based on the given information, the reaction will be,
CS2 (l) + 3Cl2 (g) ⇒ CCl4 (l) + S2Cl2 (l)
By using the standard values of the substances, the standard enthalpy of the reaction is,
ΔH° = [(-139.5) + (-58.5) – 0 – (87.3)] kJ/mol
= -285.3 kJ/mol
The amount of heat evolved for 3 moles of chlorine reacted us 285.3 kJ.
Now the number of moles of chlorine needed to react to produce 5.00 kJ is,
= 5.00 kJ × 3 mol Cl2/285.3 kJ
= 0.0526 mol Cl2
Now the volume of chlorine gas at 27degree C and 812 mmHg will be,
Volume = 0.0526 mol Cl2 × 0.0821 Latm/mol K × 300 K/ 1.07 atm
= 1.21 L
