Find the enthalpy change per mole of sodium when sodium reacts with water. 8 grams of sodium reacts with 227 cm3 of water, producing a temperature change from 298 K to 308.4 K. The specific heat capacity of water is 4.18 J/K g. A. -28.36 kJ B. 9868.1 J C. 62.75 kJ D. -28356.7 kJ

Respuesta :

Answer:

The correct answer to the following question will be Option A (-28.36 KJ). The further explanation is given below.

Explanation:

The given values are:

Sodium's mass = 8 grams

Water's volume = 227 cm³

Molar mass = 23 g/mol

Density of water = 1 g/cm³

Specific heat capacity ([tex]C_{w}[/tex]) = 4.18 J/Kg

As we know,

⇒  [tex]Moles \ of \ Na =\frac{mass \ of \ Na}{Molar \ mass \ of \ Na}[/tex]

On putting the estimated values, we get

⇒                        [tex]=\frac{8}{23}[/tex]

⇒                        [tex]=0.348 \ mol[/tex]

Now, Water's mass will be:

⇒  [tex]M_{w} = density\times volume[/tex]

           [tex]=1\times 227[/tex]

           [tex]=227 \ g[/tex]

Change in temperature will be:

⇒  [tex]\Delta T=(308.4-298)K[/tex]

           [tex]=10.4 \ K[/tex]

Heat released will be:

⇒  [tex]q=M_{w}\times C_{w}\times \Delta T[/tex]

On substituting the estimated values, we get

       [tex]=227\times 4.18\times 10.4[/tex]

       [tex]=9.87\times 10^3[/tex]

       [tex]=9.87 \ KJ[/tex]

So that the change in the solution of Na will be:

⇒  [tex]\Delta H=\frac{-q}{Moles \ of \ Na}[/tex]

            [tex]=\frac{-9.87}{0.348}[/tex]

            [tex]=-28.36 \ KJ/mol[/tex]