Does a precipitate form when a solution of calcium chloride and a solution of mercury(I) nitrate are mixed together? Write the net ionic equation.

Respuesta :

Answer : Yes, a precipitate form when a solution of calcium chloride and a solution of mercury(I) nitrate are mixed together.

The net ionic equation will be,

[tex]2Hg^{+}(aq)+2Cl^{-}(aq)\rightarrow Hg_2Cl_2(s)[/tex]

Explanation :

In the net ionic equations, we are not include the spectator ions in the equations.

Spectator ions : The ions present on reactant and product side which do not participate in a reactions. The same ions present on both the sides.

The given balanced ionic equation will be,

[tex]CaCl_2(aq)+2HgNO_3(aq)\rightarrow Ca(NO_3)_2(aq)+Hg_2Cl_2(s)[/tex]

The ionic equation in separated aqueous solution will be,

[tex]Ca^{2+}(aq)+2Cl^{-}(aq)+2Hg^{+}(aq)+2NO_3^{-}(aq)\rightarrow Hg_2Cl_2(s)+Ca^{2+}(aq)+2NO_3^{-}(aq)[/tex]

In this equation, [tex]Ca^{2+}\text{ and }NO_3^-[/tex] are the spectator ions.

By removing the spectator ions from the balanced ionic equation, we get the net ionic equation.

The net ionic equation will be,

[tex]2Hg^{+}(aq)+2Cl^{-}(aq)\rightarrow Hg_2Cl_2(s)[/tex]

Taking into account the definition of net ionic equation, a precipitate of Hg₂Cl₂ is formed when a calcium chloride solution and a mercury (I) nitrate solution are mixed.

The net ionic equation is a chemical equation for a reaction that lists only the species that participate in the reaction.

In other words, an ionic equation is a chemical equation where electrolytes in aqueous solution are written as dissociated ions. Usually this is a salt dissolved in water, where the ionic species are followed by (aq) in the equation, to indicate that they are in aqueous solution.

The balanced equation will be:

CaCl₂(aq) + 2 HgNO₃(aq) → Ca(NO₃)₂(aq) + Hg₂Cl₂(s)

where (aq) means aqueous and (s) solid.

Taking into account that:

  1. All Cl⁻, Br⁻ and I⁻ salts are soluble.
  2. All salts of NO₃⁻, C₂H₃O₂⁻, ClO₃⁻ and ClO₄⁻ are soluble.

The total ionic equation in separated aqueous solution will be:

Ca²⁺(aq) + 2Cl⁻(aq) + 2 Hg⁺(aq) + 2NO₃⁻(aq) → Ca²⁺ + 2NO₃⁻(aq) + Hg₂Cl₂(s)

A spectator ion is an ion that appears both as a reactant and as a product in an ionic equation.

Spectator ions can be either cations (positively charged ions) or anions (negatively charged ions).

When writing a net ionic equation, spectator ions found in the original equation are ignored. Thus, the total ionic reaction is different from the net chemical reaction.

In this case, Ca²⁺ and NO₃⁻ are the spectator ions because they appear unchanged in both the product and the reagent. So these ions cancel out by writing the net ionic equation and you get:

2Cl⁻(aq) + 2 Hg⁺(aq) → Hg₂Cl₂(s)

Since Hg₂Cl₂ is an insoluble salt, it will precipitate.

Finally, a precipitate of Hg₂Cl₂ is formed when a calcium chloride solution and a mercury (I) nitrate solution are mixed.

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