A sample of a compound contains 7.89 g potassium, 2.42 g carbon, and 9.69 g oxygen. Determine the empirical and molecular formulas of this compound, which has a molar mass of 198.22 g/mol.

Respuesta :

Answer:

The empirical formula of the compound = [tex]K_1C_1O_3[/tex]

The molecular formula of the compound = [tex]K_2C_2O_6[/tex]

Explanation:

Mass of potassium = 7.89 g

Molar mass of potassium = 39 g/mol

Moles of potassium = [tex]\frac{7.89 g}{39 g/mol}=0.2023 mol[/tex]

Mass of carbon  = 2.42 g

Molar mass of carbon = 12 g/mol

Moles of carbon = [tex]\frac{2.42 g}{12 g/mol}=0.2017 mol[/tex]

Mass of oxygen = 9.69 g

Molar mass of oxygen = 16 g/mol

Moles of oxygen = [tex]\frac{9.69 g}{16g/mol}=0.6056 mol[/tex]

For the empirical mass of the compound, divide the lowest moles of an element with all the moles of the elements:

Potassium : [tex]\frac{0.2023 mol}{0.2017 mol}=1[/tex]

Carbon : [tex]\frac{0.2017 mol}{0.2017 mol}=1

Oxygen : [tex]\frac{0.6056 mol}{0.2017 mol}=3[/tex]

The empirical formula of the compound = [tex]K_1C_1O_3[/tex]

Empirical mass of the compound= (39 g/mol+12 g/mol+3 × 16 g/mol) = 99 g/mol

Molar mass of the compound = 198.2 g/mol

Let the molecular formula of the compound be : [tex]K_{1n}C_{1n}O_{3n}[/tex]

[tex]n=\frac{\text{Molar mass}}{\text{Empirical mass}}[/tex]

[tex]n=\frac{198.22 g/mol}{99 g/mol}=2[/tex]

So, molecular mas of the compound :

[tex]K_{1\times 2}C_{1\times 2}O_{3\times 2}=K_2C_2O_6[/tex]