A physical change in a substance doesn't change what the substance is. In a chemical change where there is a chemical reaction, a new substance is formed and energy is either given off or absorbed.
For example, if a piece of paper is cut up into small pieces it still is paper. This would be a physical change in the shape and size of the paper. If the same piece of paper is burned, it is broken up into different substances that are not paper.
When heat is given off in a chemical change or reaction, it is called an exothermic reaction. When heat is absorbed in a chemical change or reaction, it is called an endothermic reaction. The speed at which chemical reactions take place depend on the temperature pressure and how concentrated the substances involved in the chemical reaction are. Sometimes substances called catalysts are used to speed up or help along a chemical reaction. Light is helpful in the processing of film.