Respuesta :
Answer;
Q = 359.2-J
Explanation;
Given that;
Constants for mercury at 1 atm
Heat capacity of Hg(l) is 28.0 J/(mol*K)
melting point is 234.32 K
Enthalpy of fusion is 2.29 kJ/mol
17.7-g Hg / 200.6g/mol = 0.0882 mol Hg;
°C + 273 = 298 K;
2.29-kJ/mol = 2290-J/mol
Q = (m x ΔT x Cp) + (m x Hf)
Q = 0.0882-mol x (298 - 234.32) x 28.0-J/mol*K) + (0.0882-mol x 2290-J/mol)
Q = 157.26-J + 201.978-J
Q = 359.2-J
Q=359-J (3 sig fig allowed due to 17.7-g given in problem)
The heat released is 50.3 J.
We know that;
- Mass of mercury = 17.7 g
- initial temperature of mercury = 25.00 °c
- Melting point of mercury = -39°c
- Specific heat capacity of mercury = 0.14 J/g/°c
- Heat of fusion of mercury = 11.8 J/g
Heat released when liquid mercury is converted to solid mercury is obtained from;
H = mcθ + mL
H = m(cθ + L)
H = 17.7 g[(0.14 × -64) + 11.8 )
H = 50.3 J
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