We know the heat released or absorbed in a physical process in a calorimeter, H = mass (m)×specific gravity (s)×(change of temperature). Here we can see the change of temperature is (25.3-21.4)=3.9°C. The specific gravity of water (s) is 1 at 25°C. The mass is 25+60=85g. (as density of water is 1g/mL, so 60.0mL water = 60g of water) The heat released is H = 85×1×3.9 = 331.5 cal.